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Hexamethylphosphoric Triamide is a high-boiling solvent generally used for dissolving metals or organometallic compounds, and it is particularly appropriate for conducting the discount of α,β-unsaturated ketones by alkali metals.
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Solvent: hexamethylphosphoramide_(HMPA)
HMPA is a polar aprotic solvent. Because it selectively solvates cations, it accelerates some tough SN2 reactions.
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Other alternatives to HMPA embody the N,N′-tetraalkylureas DMPU (dimethylpropyleneurea) or DMI (1,3-dimethyl-2-imidazolidinone).